近日，鄭州大學(xué)化學(xué)學(xué)院李綱教授課題組的綜述論文《質(zhì)子導(dǎo)電的磺酸基金屬-有機(jī)框架（Proton conductive metal sulfonate frameworks, DOI: 10.1016/j.ccr.2020.213747）》在ELSEVIER出版的國(guó)際知名化學(xué)期刊《配位化學(xué)評(píng)論》（Coordination Chemistry Reviews）發(fā)表。該文系統(tǒng)總結(jié)、評(píng)述了近年來(lái)具有磺酸基金屬-有機(jī)框架材料的設(shè)計(jì)策略、結(jié)構(gòu)優(yōu)勢(shì)及在質(zhì)子導(dǎo)電領(lǐng)域中的應(yīng)用前景，并對(duì)未來(lái)的發(fā)展趨勢(shì)進(jìn)行了探討。
多年來(lái)，在配位化學(xué)及材料化學(xué)領(lǐng)域，金屬有機(jī)框架材料得到了持續(xù)的關(guān)注。此類孔狀材料具有易設(shè)計(jì)和易修飾的結(jié)構(gòu)特點(diǎn)，因?yàn)槭沟闷渥鳛橐环N新興的質(zhì)子導(dǎo)體而備受關(guān)注。MOFs中磺酸基團(tuán)的不僅可以作為質(zhì)子源，還可以參與框架內(nèi)氫鍵體系的形成，因?yàn)榉浅Ｓ欣谫|(zhì)子的高效傳輸。論文按照框架內(nèi)磺酸基團(tuán)的存在形式：參與配位或者未配位只是包裹在框架內(nèi)以及通過(guò)后修飾引入磺酸基團(tuán)等，對(duì)近年來(lái)質(zhì)子導(dǎo)電性磺酸基MOFs的制備以及形成質(zhì)子導(dǎo)電復(fù)合膜等的結(jié)構(gòu)優(yōu)勢(shì)、性能優(yōu)勢(shì)進(jìn)行了全面、系統(tǒng)的分析和總結(jié)，為新型晶態(tài)固體質(zhì)子導(dǎo)體的研究和開(kāi)發(fā)提供了重要的科學(xué)參考。
李綱教授課題組近年來(lái)致力于晶態(tài)質(zhì)子導(dǎo)電材料的設(shè)計(jì)與開(kāi)發(fā)。先后對(duì)羧酸基金屬有機(jī)框架材料（Coord.Chem. Rev.2020, 403, 213100）、鋯基金屬有機(jī)框架材料（Inorg. Chem. Front. 2020, 7, 3765-3784）以及共價(jià)有機(jī)框架材料（Coordin. Chem. Rev. 2020, 422, 213465）的質(zhì)子導(dǎo)電性能進(jìn)行了綜述。
本綜述的第一作者為博士研究生劉瑞蘭，李綱教授為通訊作者，鄭州大學(xué)為通訊單位。
論文信息：
https://www.sciencedirect.com/science/article/pii/S001085452031198X題目：Proton conductive metal sulfonate frameworks作者： Rui-lan Liu 1, Dan-YangWang 1, Jin-Rui Shi, Gang Li*Coordination Chemistry Reviews 431 (2021) 213747. DOI：10.1016/j.ccr.2020.213747
通訊作者簡(jiǎn)介：
鄭州大學(xué) 化學(xué)與分子工程學(xué)院鄭州大學(xué)化學(xué)學(xué)院 (199607-現(xiàn)在)
University of Sussex 博士后 (200409-200509)香港中文大學(xué)訪問(wèn)學(xué)者 (200401-200407)
榮譽(yù)稱號(hào)及獲獎(jiǎng)
教育部新世紀(jì)優(yōu)秀人才 (2010)；河南省優(yōu)秀教師 (2012)；寶鋼教育優(yōu)秀教師獎(jiǎng)(2013) ；河南省高等學(xué)校中青年骨干教師 (2006)；河南省教育廳學(xué)術(shù)技術(shù)帶頭人 (2005)；河南省優(yōu)秀碩士論文指導(dǎo)教師 (2013& 2012)；鄭州大學(xué)優(yōu)秀碩士論文指導(dǎo)教師 (2013&2012)；鄭州大學(xué)“三育人”優(yōu)秀個(gè)人 (2012 &2008)；鄭州大學(xué)第二屆講課大賽二等獎(jiǎng) (2007)
研究領(lǐng)域
設(shè)計(jì)特定的MOFs、HOFs以及COFs，揭示其在傳感、能源等領(lǐng)域的應(yīng)用前景
近期論文
X.-X. Xie, Y.-C. Yang, B.-H. Dou, Z.-F. Li, G. Li*. Proton conductive carboxylate-based metal-organic frameworks. Coordin. Chem. Rev., 2020, 404, 213100.DOI: 10.1016/j.ccr.2019.213100. https://www.sciencedirect.com/science/article/pii/S0010854519304126
Y. Qin, T.-L. Gao, W.-P. Xie, Z. F. Li, G. Li*. Ultrahigh proton conduction in two highly stable ferrocenyl carboxylate frameworks. ACS Appl. Mater. Interfaces, 2019, 11, 31018?31027. https://doi.org/10.1021/acsami.9b11056
R. L. Liu, Y. R. Liu, S. H. Yu, C. L. Yang, Z. F. Li, G. Li*. A highly proton conductive 3D ionic cadmium-organic framework for ammonia and amines impedance sensing. ACS Appl. Mater. Interfaces, 2019, 11, 1713-1722. https://doi.org/10.1021/acsami.8b18891
X. Liang, B. Li, M.H. Wang, J. Wang, R.L. Liu, G. Li*. Effective approach to promoting the proton conductivity of metal?organic frameworks by exposure to aqua?ammonia vapor. ACS Appl. Mater. Interfaces, 2017, 9, 25082–25086. https://doi.org/10.1021/acsami.7b07635
R. L. Liu, Z. Q. Shi, X. Y. Wang, Z. F. Li, G. Li*. Two highly stable proton conductive cobalt(II)-organic frameworks as impedance sensors for formic acid. Chem. - Eur. J., 2019, 25, 14108 – 14116. https://doi.org/10.1002/chem.201902169
Z.B. Sun, S.H. Yu, L.L. Zhao, G. Li*. A highly stable two-dimensional copper(II)-organic framework for proton conduction and ammonia impedance sensing. Chem. - Eur. J., 2018, 24, 10829– 10839. https://doi.org/10.1002/chem.201801844
X. X. Xie, Z. H. Zhang, J. Zhang, L. F. Hou, Z. F. Li, G. Li*. Impressive proton conductivities of two highly stable metal-organic frameworks constructed by substituted imidazoledicarboxylates. Inorg. Chem. 2019, 58, 5173?5182. https://doi.org/10.1021/acs.inorgchem.9b00274
K.M. Guo, L. L. Zhao, S.H. Yu, W.Y. Zhou, Z.F. Li, G. Li*. A water-stable proton conductive barium(II)-organic framework for ammonia sensing at high humidity. Inorg. Chem., 2018, 57, 7104-7112. https://doi.org/10.1021/acs.inorgchem.8b00806
R. L. Liu, L. L. Zhao, W. Dai, C.L. Yang, X. Liang, G. Li*. A comparative investigation on proton conductivities for two metal-organic frameworks under water and aqua-ammonia vapors. Inorg. Chem. 2018, 57, 1474–1482. https://doi.org/10.1021/acs.inorgchem.7b02851
R. L. Liu, L. L. Zhao, S. H. Yu, X. Liang, Z. F. Li, G. Li*.Enhancing proton conductivity of a 3D metal?organic framework by attaching guest NH3molecules. Inorg. Chem. 2018, 57, 11560?11568. https://doi.org/10.1021/acs.inorgchem.8b01606
