低價(jià)鈦[如TiCl3/LiAlH4生成的Ti(0)]催化羰基制備烯烴的反應(yīng)。此反應(yīng)是單電子轉(zhuǎn)移歷程。
反應(yīng)機(jī)理
反應(yīng)實(shí)例
參考文獻(xiàn)
1. (a) McMurry, J. E.; Fleming, M. P. J. Am. Chem. Soc. 1974, 96, 4708-4712. (b) McMurry, J. E. Chem. Rev. 1989, 89, 1513-1524. (Review).
2. Hirao, T. Synlett 1999, 175-181.
3. Sabelle, S.; Hydrio, J.; Leclerc, E.; Mioskowski, C.; Renard, P.-Y. Tetrahedron Lett.2002, 43, 3645-3648.
4. Williams, D. R.; Heidebrecht, R. W., Jr. J. Am. Chem. Soc. 2003, 125, 1843-1850.
5. Honda, T.; Namiki, H.; Nagase, H.; Mizutani, H. Tetrahedron Lett. 2003, 44,
3035-3038.
6. Ephritikhine, M.; Villiers, C. In Modern Carbonyl Olefination Takeda, T., Ed.; Wiley-VCH: Weinheim, Germany, 2004, 223-285. (Review).
7. Uddin, M. J.; Rao, P. N. P.; Knaus, E. E. Synlett 2004, 1513-1516.
8. Stuhr-Hansen, N. Tetrahedron Lett. 2005, 46, 5491-5494.
9. Zeng, D. X.; Chen, Y. Synlett 2006, 490-492.
10. Duan, X.-F.; Zeng, J.; Zhang, Z.-B.; Zi, G.-F. J. Org. Chem. 2007, 72, 10283-10286.
11. Debroy, P.; Lindeman, S. V.; Rathore, R. J. Org. Chem. 2009, 74, 2080-2087.
編譯自：J.J. Li, Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications, McMurry coupling，page 370-371.
