此反應(yīng)是Polonovski反應(yīng)的改進(jìn)反應(yīng)，但是反應(yīng)條件溫和，C-N鍵沒有斷裂，產(chǎn)物得到的是β-胺基α,β-不飽和三氟甲基酮。
反應(yīng)機(jī)理
反應(yīng)實(shí)例
參考文獻(xiàn)
1. Ahond, A.; Cavé, A.; Kan-Fan, C.; Husson, H.-P.; de Rostolan, J.; Potier, P. J. Am. Chem. Soc. 1968, 90, 5622–5623.
2. Husson, H.-P.; Chevolot, L.; Langlois, Y.; Thal, C.; Potier, P. J. Chem. Soc., Chem. Commun. 1972, 930–931.
3. Grierson, D. Org. React. 1990, 39, 85–295. (Review).
4. Sundberg, R. J.; Gadamasetti, K. G.; Hunt, P. J. Tetrahedron 1992, 48, 277–296.
5. Kende, A. S.; Liu, K.; Brands, J. K. M. J. Am. Chem. Soc. 1995, 117, 10597–10598.
6. Renko, D.; Mary, A.; Guillou, C.; Potier, P.; Thal, C. Tetrahedron Lett. 1998, 39,
4251–4254.
7. Suau, R.; Nájera, F.; Rico, R. Tetrahedron 2000, 56, 9713–9720.
8. Thomas, O. P.; Zaparucha, A.; Husson, H.-P. Tetrahedron Lett. 2001, 42, 3291–3293.
9. Lim, K.-H.; Low, Y.-Y.; Kam, T.-S. Tetrahedron Lett. 2006, 47, 5037–5039.
10. Gazak, R.; Kren, V.; Sedmera, P.; Passarella, D.; Novotna, M.; Danieli, B.
Tetrahedron 2007, 63, 10466–10478.
11. Nishikawa, Y.; Kitajima, M.; Kogure, N.; Takayama, H. Tetrahedron 2009, 65, 1608–1617.
12. Perry, M. A.; Morin, M. D.; Slafer, B. W.; Rychnovsky, S. D. 2012, 77, 3390–3400.
編譯自：Name Reactions （A Collection of Detailed Reaction Mechanisms）, Jie Jack Li, Polonovski–Potier reaction，page 488-489.
